For anyone who hits this:
Try version="3.0" - it stands for EJB version, not XSD version. I believe the XSD self-documentation is wrong, see JBMETA-293 .
<jboss xmlns="http://www.jboss.com/xml/ns/javaee" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.jboss.com/xml/ns/javaee http://www.jboss.org/j2ee/schema/jboss_5_0.xsd" version="3.0">
See http://ondra.zizka.cz/stranky/programovani/java/ejb/ejb3-howto.texy
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