You should start with the docs first
http://www.jboss.org/jbosstm/docs/index.html
And there is also a short wiki article on using JTS
https://www.jboss.org/community/docs/DOC-13179 which was written for a later version than
the one you are using but it may still be of use.
And there is lots of stuff on the web which google should pickup.
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